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You're better off saving before the fight, catching the Shadow Pokemon, purifying it, checking it's nature and resetting again.
If I remember correctly you can't see the natures on Shadow Pokemon until you purify them... but I could be wrong.
In other words, it's a huge headache.
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Nah, I think it shows up after you've gotten down to the last (or next to last) bar on the shadow meter. If you're going for specific natures, I suggest catching the Pokemon in another game where it's easier. |: