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battling has a lot of strategy involved. if you want to use a pokemon in a different tier then OU then you want to make sure that it has an effective move set, nature, EV's ect. additionally you want to make sure that you have other pokemon on your team that can support it and vice versa. good synergy on a team is also important. but if you want to learn more about tiers and usage then you can check out the links in the posts above.
hope this helps you a little =)
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