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Old January 18th, 2013 (01:56 PM).
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Quote originally posted by Hikari10:
It's called a "critical capture", and it happens randomly but the actual probability has not yet been calculated.

Most critical captures usually catch the Pokemon successfully but there is still a chance of it escaping from the Poke Ball.

So yeah, question answered!
There's been a calculated version here: http://www.serebii.net/blackwhite/capture.shtml

It depends on how many Pokemon you've caught.
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