For non-pokemon stuff, here's some of my better original Sailor Moon characters. I have lots of it, so if you actually want to see more I can post more.
I'm guessing that once you make the shape and it hardens (after you bake it), you paint it?
Yeah, you only paint it after all the pieces are baked. Then after you paint it, if you didn't connect the parts before painting, you glue the parts together.