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As most of Grimer's sprites seem to depict a tongue of sorts, one can assume that under all of that sludge that makes up the majority of its body, there's a thin, extremely flexible membrane that keeps its organs in place, and is also what would allow Grimer to have distinct arms.
Slugma would also seem to have similar tissues that divide its organs from the magma that oozes from all over its body, giving it a loose shape. Touching a Slugma of course would not be recommended, and likely lead to serve burning, or at least that's what its appearance would lead you to believe. Apparently, it has the ability to cool itself rapidly enough to allow people and Pokémon to touch it without being burned, while still staying at a temperature high enough to keep the rest of its body in a magma state. For whatever reason, Slugma uses this ability in Pokémon battles to keep itself from seriously injuring opponents, even when they have a major advantage over it otherwise, being the only explanation for why striking a non-Flame Body Slugma with a physical attack won't cause the attacker to inflict burns on themselves.
I myself am somewhat curious to how Porygon would feel by a textural standpoint. HeartGold/Soul Silver and the Mystery Dungeon series show that it apparently has some way of exerting sweat, implying that its surface isn't completely flat and has pores unidentifiable to the naked eye, yet Pokémon Ranger and Crystal version seem to indicate that most of its body is hollow, and that its outer layer is thin and rigid, so there would be no way to store any "sweat" inside of it. Porygon can also change it's body texture to other types, which adds even more questions regarding to how a "bug" or "psychic" surface would feel like.
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