Quote:
Originally Posted by RickySlaughter
Pokemon Diamond - Master Ball from Leaf Green
Pokemon Platinum - Master Ball from Platinum
It really never fails. I heard there was a glitch if you overuse Master Balls, there are slim chances that it may fail. But that is off topic I guess d:
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Got a link that can show that, AFAIK the formula never changes, and a Master Ball has a catch rate of 255x so it will never fail...
Source : Bulbapedia's Poké Ball and Catch Rate article (cant link : <)