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Once you use Psycho Boost, you should switch out before using it again (unless if you have a White Herb). Since Deoxys-FR has terrible defenses, you should use it to OHKO every opponent and not take a hit, so I also don't recommend using it in game to help train other Pokemon. Also, don't transfer it to Emerald because Deoxys-E is not very good. Sure, it's faster than any other poke, but it doesn't have anything awesome about it like Deoxys-FR's awesome sweeping potential or Deoxys-LG's abillity to take any hit. Take care.
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