There are many great Pokemon, individually good for their own special reasons.
Some may include double status infecters.
Standard EVs include may be.
4 HP/252 Def/252 Sp Def
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Nature: Bold/Calm
EVs: 4 HP/252 Def/252 Sp Def
-Toxic
-Synthesis
-Giga Drain
-Leech Seed
no sucks. Giga Drain is a piss move on Megaium, use HP Grass or Razor Leaf. Counter is better than Toxic though I prefer Swords Dance Meganium in every single way.
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Nature: Calm
EVs: 4 HP/252 Def/252 Sp Def
-Confuse Ray
-Rest
-Will-o-wisp
-Flamethrower
It can't rest that effectively and your EV spread sucks seeing you should always focus more on HP then on Defences if Base Defence+Base Special Defence > Base HP. It needs at least 301 Speed to outspeed Jolly Hitmonlee.
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Nature: Bold/Calm
EVs: 4 HP/252 Def/252 Sp Def
-Toxic
-Rest/Wish
-Confuse Ray
-Mean Look
That thing sucks because it can just be outstalled by things like Blissey. Needs Taunt and Batton Pass
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EVs: 4 HP/252 Def/252 Sp Def
-Confuse Ray
-Toxic
-Rest/Mean Look
-Shadow Ball
Same thing with Umbreon. It needs Pain Split seeing it works well with its low HP stat. Seismic Toss or Focus Punch is better than Confuse Ray.
Then you got Passers. Their main job is to pass special effects from moves such as Calm Mind, Substitute, Agility, Sword Dance, etc.
Many Passers have EVs in Speed to power up quick and it on.
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Nature: Jolly
EVs: 252 HP/4 Def/252 Spd
-Silver Wind
-Agility/Iron Defense
-Sword Dance
-Baton Pass
Doesn't need so much Speed. Baton Pass Scizor should always focus more on defences.
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Nature: Timid
EVs: 252 HP/4 Def/252 Spd
-Psychic
-Baton Pass
-Calm Mind
-Wish
Too much Speed and it can't pass Wish to save his life
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Nature: Jolly
EVs: 252 HP/4 Def/252 Spd
-Agility
-Silver Wind
-Sword Dance
-Baton Pass
Why would you give Salac on something that has Speed Boost. Liechi or Leftovers all the way
Mr.
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Nature: Timid
EVs: 252 HP/4 Def/252 Spd
-Calm Mind
-Encore
-Baton Pass
-Psychic
Not much too say excpect that it has too much Speed
There are many more.
Then there are Pokemon that should just attack right away. They usually have high Atk, Sp Atk, and/or Speed and low Defensive stats.
Their EVs may include Atk/Sp atk and Speed.
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Nature: Lonely
EVs: 4 HP/252 Sp Atk/252 Spd
-Earthquake
-Hydro Pump
-Ice Beam
-Double-Edge
I fail to see why anyone would use Petaya AND Double-Edge. Ice Beam/Surf or Hydro Pump/Crunch/Substitute or Earthquake
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Nature: Rash
EVs: 4 HP/252 Sp Atk/252 Spd
-Earthquake
-Hydro Pump
-Ice Beam
-Double-Edge
Wailord always needs to focus more on Defences THEN his attacking stats and Speed which is almost uneeded on him.
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Nature: Hasty
EVs: 4 HP/252 Sp Atk/252 Spd
-Fire Blast
-Crunch
-Shadow Ball
-Sludge Bomb
The last two moves are pointless. HP Grass/Substitute or Pursuit over them. Fire Blast is piss poor on him due to low accuracy. I'd use Overheat because he doesn't stay in for more than one or two turns
Few of the many examples.
Note that these are examples of some EVs these Pokemon can possibly have. Also know that this isn't how you have to use your Pokemon, though they can be used in that way. Many of these natures can vary espcially if you have all physical attacks or all special attacks. There are many ways this can be revised.