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You ask people you know to pair with you. Pretty simple... then you post in the pairing thread of who you pair with (username).
Asking people you know is really the only way to get a pair. Unless you want to advertise that you are looking for one in your signature. Then creepy people would take the initiative and make a move on you. :>
To put it simply: just ask. There's no set form you have to fill out, and it's not a compulsory thing at all. Most pairs are just really good friends, some are more than that, but most just enjoy each other's company a lot. Which is probably why you should VM the first person you see and ask him/her to pair with you, 'cause the answer will probably be no. Don't feel under pressure to get one, 'cause it's all just fun and (as I said already) no one's forcing you to do it. For future reference though, we do have a Pairing Thread but that's only for listing pairs, not setting yourself up with one.