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To get Power Combos. Swallow two enemies that provide you with Special Powers in one gulp. That is perhaps, the easiest method. There are others.
Inhale an enemy with a Special Power, and then exhale it towards another enemy with a Special Power. Swallow the Combo Star that appears.
This method is similar to the one above. Rather than exhaling the first enemy. Just press L or R and you end up lifting the enemy. As above, you then hurl the enemy at another enemy.
Another evolution. This time you lift the enemy once it's been swallowed. This gives you a Power Star. Throw the Power Star at the enemy and you'll earn a combo star.