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I chose Ash, Brock, and Misty because they were the three main characters of the first few seasons. I would have chosen Jessie and James, but I couldn't since they weren't on the list...
I haven't played 3rd Gen in such a long time.
I think my teams were:
Leaf Green:
Blastoise
Dodrio
Nidoking
Jolteon
Hypno
Ninetales
Emerald:
Blaziken
Ludicolo
Pelipper
Flygon
Manectric
Gardevoir