Samurott, Beartic, Cofagrigus, Klinklang, Liepard and Garbodor.
(Sorry if I messed up on this one. I honestly haven't beaten an Unova game)
Thanks and for you
Seismitoad, Vanilluxe, Chandelure, Bisharp, Hydreigon, and Scolipede
Sorry some of these types are kinda lacking in the 5th Gen games