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...Um, let me look real quick...according to this list here, three Pokemon start with 'Q', and only one starts with 'X'. And that may not include any Gen. V Pokemon, for all I know.
I'm sure this one was here already, but...the first one that came to mind.
By the way, according to Bulbapedia, Sceptile has the highest base Speed stat out of all the fully evolved starter Pokemon. Well, last time I checked, anyways.
It's okay if the Pokemon have been used. Not only has all of 'em have probably bee used already, some have been used various amount of times, due to the minimal amount of Pokemon for a particular letter. 'Y' for example.