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I have honestly never leveled a pokémon up to Lv 100. I guess I'm just not patient enough after the E4 has been beaten and the story has ended. Pity though, it would be cool to actually have a maxed out creature on my team at some point.
It was an Ampharos in my original Gold Version. The thing knew Zap Cannon, Thunder Punch, Thunder, and Dynamic Punch. I was quite the baller back in the day.
I think it was a Beedrill that I used rare candy a lot to raise it to level 100 after doing the Old Man/Missingno trick. I've never levelled a pokemon all the way up to level 100 without using any rare candies.