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From the gifsets I've seen on tumblr (really, that's my source for finding anime to watch lately... all from one account |D), the character design doesn't look half bad. Maybe I should give the show a go, then?
Though I have to admit that I like Hoshino's style in DGM more than what I've seen of Psycho Pass.
Talking about collaborations, I heard that SateLight (the guys responsible for Macross) are working on a project together with Kazuki Yone (the artist of Hakuouki, Hiiro no Kakera and a bunch of other Otome games (I think?)). I love her style and I wished it was an anime instead of something live, because from what I've seen the art and character design look great.