I think, White 2 is widely recommended because it provides many Pokémon that you can find (there are whooping 300 in the Dex there), and there are more features like battling Gym Leaders from other regions, having a mall to your own liking, making a film in-game and all. Basically it's like the original Pokémon White, but better.
However, if you're looking for the story and want to enjoy it, I would recommend you to play the original White first. I'm sure White 2 can be played without playing the original White first, but it would be more enjoyable if you finished White first. Anyway, the decision is up to you.