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I have to go with the lati@s siblings. Simply because they are strong willed, not picking fights for entertainment, but can stick up for each other and fight hard enough to stop a tsunami.
I'd say easily Mewtwo. Judging from Mewtwo Strikes Back and Mewtwo Returns, he is easily to the likes of my eyes the most powerful Pokémon to date. Though those movies were made a long while ago and this is probably outdated, I'm not much of a new anime fan as I should be.
Without counting movies, I'd say Pikachu, whose plot armor deeply annoys me, with Ash's Charizard being a close second (particularly after training in Charicific Valley).