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Mmmm...I use renders already w/o a background~ It's much more easier that way~
I don't really use images w/ a background, but If I must, I just use the eraser tool set to 0% hardness and just try to erase the background.
Another way is to use the 'Magic Wand Tool.' Yeah not going into detail w/ that~ o.O
But for the most part, 95% I use renders or images w/o backgrounds~ :)