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Ok, I'll make a copy of them before I start EV training them, just in case you're not satisfied with the results. Is there a specific moveset you want for any of them?
You can pick on all of them which stats you want maxed out. I just choose two of the highest stats for each one. Empoleons highest stats are Sp.Atk and Sp.Def. You can only max out 2 stats or spread 252 EVs to 2 stats and 6 EVs to one other stat.
Well I pick one's with the perfect nature. I was thinking of doing the EV spread like this, but I'm not sure if that's ok with you.
Darkrai 255Sp.Atk/255Spd
Zangoose 255Atk/255Spd
Turtwig 255HP/255Atk or Def
Chimchar 255Atk/255Spd
Piplup 255Sp.Atk/which ever other stat you want maxed out.
It's fast but there are a few things I have to ask first. Do you mind if I spread pokerus to them, what EV spread do you want for each pokemon, and what moveset do you want for each one?