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I have a picachu at level 60 and by now i dont think that its going to learn anything else but do you know about bolt tackle? does he learn it? can i get it in a TM?
Volt Tackle is only learned through breeding, by having a female Pikachu/Raichu hold a Light Ball and breed it with something. The result is a Pichu with Volt Tackle.
My Nintendo Player's Guide says the Light Ball does occasionally show up on wild Pikachu, apparently. Maybe once I have time, I'll spend some time trying to get one.
It took me 4 days to get a light ball (caught a box of pikachus)
answer is yes it does learn same way at emerald. btw if you have a pokemon with static at first slot chance of running intoı a pichu or pikachu at mansion greatly increases.