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While soft-resetting Ruby to try and get a shiny mudkip, I encountered a gold poochyena. Needless to say I was pissed that I had no pokeballs that early in the game. >_<
Actually I saw a shiny wooper (aside from the obvious one) on pokemon silver first. I never saw one on Pokemon Ruby/Sapphire/Emerald. The next shiny was on Pokemon Diamond--it was a Roselia.
Mine was poochyena. When i saw it i nearly had a heart attack. Luckily i had a couple of great balls and captured it. Sadly that file is long gone. Oh why Poochyena did you leave me so.
I forgot about the shiny Golbat I caught in Sky Pillar many years ago in Ruby... I transferred him to my Diamond, which unfortunately got its file deleted by a hacked Pokemon from the GTS...
Other than the *obvious* red Gyarados, I've caught a purple drowzee on pokemon gold. Seen that one a bazillion times...
Other ones I've seen on pokemon gold and crystal are blue gastly (I've also caught that one a bunch of times too), green zubat (didn't have any pokeballs!!!), and yellow caterpie. There's probably a couple more that I am forgetting...
On pokemon ruby (or was it emerald?), I caught a yellow poochyena twice.
Fire red I got a shiny (I think it was yellowish) spearow and a yellow caterpie.
On platinum and pearl I've caught a pink purugly and a light-colored bidoof.
Already posted this like a million times, but: Orange Graveler on Pearl.
Others i had:
- Golden Bidoof (couldn't save on that file because i didn't delete the old game, i just wanted to see how far i get without saving, Pearl)
- Green Onix (Crystal)
- Gray Rattata (Silver (?))