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The best one in GSC is Red Gyarados (nn Mr. Slave). He can get you Strength and the 3 Water HMs, and since he looks bad and sucks, it's probably the most value you'll get out of him.
totodile because it can learn surf and can gain an advantage over chikorita when you go to goldenrod because then you can get ice punch so my usual learnset for totodile is :
slash surf crunch and ice punch