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My first shiny Pokemon I ever received on my copy of Diamond was my Haunter. I was so excited I wasted my only Master Ball on him because I was scared he'd get away. D:
Hmmmm...my shiny pokemon were 2 ralts hatched by using rng abuse,charmander traded from my diamond and riolu luckily hatched from the egg riley gave.....
LOL @ OP saying his first shiny happened to be the first Phione Egg. In diamond my first was a male Modest shiny Gastly that I chained for and synchronized for
Mine was a shiny Luvdisc... and I hate Luvdisc D: Well I lost it somewhere along the line so even if I wanted it it's gone now <: But recently I started chaining and now I have a shiny Shinx, Buneary, and Buizel(Now Floatzel :3).
My First Shiny I caught in Pokemon Diamond (And My First Shiny Without any Cheats) Was Shinx at the beginning of the game, Used it throughout and now it's a Shiny Luxray :P No AR or nothing, I was so lucky :)
My first shiny was a shiny Rattata. But I was little, and I didn't know the value of a shiny at the time... So I killed it and went on my merry way, to then regret it 6 years later :)