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Well... Heatran's catch rate is 3 so.. it'll be pretty hard. Use this catch rate formula to figure out how much of a chance you have of catching Heatran. Carry plenty of Quick Balls, Timer Balls and Dusk Balls, as these will be most effective.https://bulbapedia.bulbagarden.net/wiki/Catch_rate
I'd suggest using.... maybe a level 55 Ground type? They really dish out the hurt to Heatran, but the level is so you won't kill it. Victory Road is the perfect place to catch such a poke.
Omg, it took me hours catching Heatran with an Ultra ball. It probably took me 30 something times, but that was my pearl version. In my diamond version I caught it with a dusk ball and it took me like 13 times, so I'm guessing try to catch heatran with a dusk ball cuz its in a cave and make sure ur doing it at night time as well. lol ;D
There isn't really a discussion going on here and the basis of this thread could go into the Q&A thread... but since a number of people have posted in this thread (some with answers, some not) and a lot of them are posts not really suited in the Q&A nor valid as any kind of discussion, I'll just close this up. Please be sure to post any further questions in the Q&A thread.