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My first Pokemon in Diamond that I caught was a Starly. In Platinum, I caught a Zubat first. I already had my team planned out, so I didn't bother with anything else.
Wow, that was a long time ago. I wanted a Grass team... so I battled my way all the way to Pastoria with just Turtwig/Grotle until I could go into the Great Marsh... where I caught Carnivine! Then I proceeded to catch a Snover.