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I liked Acro for a while, it was easy to handle, etc...but in my latest playthrough I've decided to try the Mach, just to see how it is. Yeah, it's better...
Mine was a lame Ratata, the little rascal managed to break 3 of my 5 Pokeballs, but in the end I got him. Ended up being one of my first to grow up to lvl. 99.