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You are trying to patch a 7z file. I think that that is what you are doing wrong. Download 7z o use winrar to open that file and extract the .nds that is inside.
Hello! I have a question, did you adapt frontier brain's teams to the new PSS split, abilities and moves that you introduced? It's just that the thing that I love the most from Emerald is the Battle Frontier! And, well, I know that one can perfectly challengue it as it is but it's just curiosity...