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Yes. According to the Ru/Sa Player's Guide Shroomish learns Spore at level 54 and cannot learn that once it evolves into Breloom. But Breloom can learn, if you evolve it at level 23: Mach Punch, Counter, Sky Uppercut, Mind Reader and Dynamicpunsh.
Leave it as a Shroomish until it learns spore. Evolve it immediately then. Teach it Brick Break(if you dont' want to waste the tm, use the heart scale to bring back sky uppercut), bulk up and return, and you got yourself the standard breloom killing machine (with adamant personality of course ^_^)
Leave it as a Shroomish until it learns spore. Evolve it immediately then. Teach it Brick Break(if you dont' want to waste the tm, use the heart scale to bring back sky uppercut), bulk up and return, and you got yourself the standard breloom killing machine (with adamant personality of course ^_^)