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My first level 100 (that I actually own) was my Palkia. xD Man, I overused that thing.
My first level 100 that I trained was my cousin's Infernape. 'Cause we were such n00bs then, my cousin asked me to train his infernape for him. I was like, yeah sure, as long as you train up my Infernape. So we switched Infernape. I made good on my promise and trained that sucker up to level 100, and he didn't do crap to my Infernape at all and I was like, I beat the game with your Infernape, it's level 100 now! And I had put some really good moves too, and then I get my Infernape back and I was like; WTF man, you didn't train up my Infernape at all. He was like, oh yeah, I forgot. I beat the game though (smile smile smile). v_v Since I don't really get to see him alot, I battled him and the Infernape later. It ends up he totally changed my moveset (Flame Wheel, Close Combat, Shadow Claw, and something else) to (Rock Smash, Cut, Rock Climb, Strength). ;~; I was so sad.
My second level 100 (and my last one) was a Dragonite that I had trained up. I had a second Dragonite that was on its way to level 100 and my cousin (the Infernape one) had asked for my Dragonite in return for something, I don't really remember. Being a n00b, I said yes. My moveset was (Dragon Dance, Outrage, Wing Attack, and the strongest rock attack, I forgot what it was called). My cousin changed it to (Thunder Punch, Thunder Bolt, Charge Beam, and another move that I've forgotten) D= My poor Dragonite. ;~;
Sorry for the rantish thing. xD Still kind of mad about it.