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I'd go for Dustox. Sure he's an ugly moth, and his powers aren't the best. but the first Wurmple I caught evolved into a Dustox, and that sucker has been there for me ever since.
Red-haired Shanks from One Piece
Straight Cougar from s-CRY-ed
Ganondorf from The Legend of Zelda Series
Mugen from Samurai Champloo
Lil' Slugger from Paranoia Agent