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Not on my game. Because my brother's best char is Mario. XD
Anyway, it's kind of hard to pick. I will break it down (below).
Donkey Kong = A big Ape with a red tie that likes lots of barrels.
Or
Mario = A Short Italian guy that shoots fire balls and has all red clothes on.
(XD)
If I had to pick one then I guess I would pick Mario, because them fire balls hurt. XD
Well, Donkey Kong is stronger, but Mario is a small target compared to DK. And unless DK has orange grenades and that coconut gun, Mario would probably beat DK.
I like Mario better, I think that Donkey Kong for SNES was good,and all, but Mario is just better. If they were to get in a fight, Mario would pull off some tricky moves, while Donkey Kong would just be slow and lose XD.