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Charmander, definitely. It's too cute for words and when it evolves it becomes the amazing Charizard... ^_^
I think my least favourite is Bulbasaur, seeing as Ivysaur and Venusaur aren't very good looking...
My very first Pokemon game was Pokemon Gold. The starter I got was a Totdile and I named it "Crocket" he's always been, and will always be, my favorite starter.
I also would like to point out that my least favorite is Torchic because the idea of a "Fire Chicken" is just retarded (IMO).