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You have to connect to Wi-Fi once before you are able to get your Friend Code. Once you do, you look in your Pal Pad for it, and you get the Pal Pad from the lower floor in the Pokémon Center.
Go to a Pokemon Center and visit the ladders/stairs on the bottom right of the pokemon center. You should be downstairs of the Pokemon Center. If it's your first time the lady at the reception counter downstairs will greet you and tell you about WiFi. After she finishes talking, talk to one of the two lady's that have not talked to you yet and then they will say you don't have a friend code and they will say would you like one? Say yes, BUT you have to already have a wireless internet connected or you cannot get your FRIEND CODE, she will also give you a Pal Pad. After that you can go onti wifi and add people to your Pal Pad. Also next time before posting search through this thread, and it tells you how to get your friend code. Thanks =D