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Master Balls

Kanto series = Featured Pokeballs and Safari Balls (The green and white ball seen in the first episode must be a Safari Ball and Ash caught 30 Tauros with the same balls, althought they are kept on normal Pokéballs.)

Johto= Featured Pokéballs, Lure Balls, Heavy Balls and Fast Balls

Hoenn= Featured Pokéballs, a Masterball (movie cameos= Repeat Ball and Luxury Ball).

In generation IV (Sinnoh) = All pokéballs (including Great- and Ultraball) until the the generation appear, but only in one of the series endings.

No more Balls where introduced.
 
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