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That's a good strategy, and most people use it. First Rare Candy your poke to level 100 so it doesn't earn EVs (this way you will be able to defeat any in-game poke). This can be accomplished more easily if you use pick-up to get Rare Candies. Next, use vitamins in the appropriate stats, and finish with some training (and use the Macho Brace to help speed up the EV training). Take care.