Ash~ Teh main character of the whole Pokemon show! He's stubborn and very adamant, I appreciate that, loyal and quite friendly to all his pokemon. His will is great, although he may act a bit dense sometimes. Ash has a great determination that can get past anything once he tries.
May~She pwns. I love her addition to the team, a girly girl kind of thing. I think it's just what the boys need, considering she IS the only girl. I like her humor, sense of a small but growing will, and the cheerful nature that brightens up the others. I also love it when she joins in a pokemon contest.
Max~he's a little scholar, loves to correct people, and how he acts with his intellectual sense is quite amusing to watch. XP I loved the episode when Ash and Max first met, that was funny. And by the size, he's a graduate of Misty's school of pulling-Brock's-ear-away-from-the-girls.
Brock~What can I say, he's a great flirter. That brings some humor into the company, also with his great cook, his matured guide and all. Brock, I mostly like for his companionship, helpfulness, and he's just too darn funny sometimes.
Pikachu~Ah, the most popular pokemon it seems. Pikachu is funny, with its own small adventures, a very loyal pokemon, and packs a punch with its thunderbolt. It can't be away from Ash, bond between Pikachu and him quite strong. It's touching to watch, and its more fun by staying not inside its pokeball.
Jessie~Hey fiery attitude is just what wimpy James needed. I admire Jessie for her hot temper, it often leads to nothing but more trouble. She's funny to watch sometimes, and with her outright bursts.
James~Eek James is nothing but an innocent scared rocket without Jessie to aide him. He's funny with hit virtuous yet a bit dumb questions sometimes, but he's overall a decent guy wanting to be bad for somer reason. oO;
Meowth~Everyone lovest he talking meowth...don't we? His plans end up going down, and sometiems, Meowth says the most random things ever. I love his side trips, such as the short Pikachu films, in which he travels without TR, giving him a more distinct perspective than before.
My fave character has to be May. ^_^ Although I still miss Misty...