when do you evole your pokemon wtith a stone...?

When it learns a move I want it to have.
 
It depends. For example, I'll level up an Eevee until it learns Bite, then let it evolve. But if I'm happy with the pokemon's current moveset and I know when it'll learn a particular move, then I'll let it evolve.
 
I don't evolve them as soon as possible. I train it until it has the move I want. Then I evolve it. I got my lesson one day in Leaf Green when I didn't evolve Pikachu at the right time. He was always the first pokemon to faint.
 
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