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All are good, but I personally like Charizard and Scizor. Groudon may be a legedary Pokemon, but I just don't like him. In fact, I hardly use him on my game. Nidoking is alright, though I like Nidoqueen better.
Out of those four? I think Charizard's pretty cool. Nice range of attacks, and a decent type. Groudon's good too. I've never been a big fan of the Nido family, or of Scizor, though I don't mind Scyther. ^^;;
I think CHARIZARD because NIDOKING and GROUDON can't affect it with ground attacks because CHARIZARD is part flying and SIZOR is weak aginst CHARIZARD.