Most of the people I've wanted to become friends with, I've randomly added them to MSN messenger, or sent them a random visitor (or personal; depending on availability to contact them through visitor messages or not) message.
The first person I wanted to be friends with on PC, before I joined, was Andy. I randomly added him to my contact list and then was too intimidated to send him a message.
The second person I wanted to be friends with on PC, soon after I joined, was Erica. Though, through Andy is how I met her. So, I didn't know who she was until I talked to Andy and he spoke about his friends and I think he linked me to some of their profiles.
The next person I wanted to be friends with was Morkula. I don't remember the story behind talking to him, but I think I asked him for his messenger through PM and he gave it to me. It was later I discovered that he didn't do that to just anyone, and we developed a friendship over time. Recently it's gotten really strong if I do say so myself. I look to him as an older brother and he displays the strongest interest out of all of the people on PC of what I'm doing with my life and how I am.
The next person is Luke (Forgotten Memory). I really can't remember why I wanted to start talking to him or what happened. I should ask him and then edit this.
The third to last latest person I wanted to befriend was Ausaudriel. I wanted to become friends with him due to his username. I became in love with the name Ausaudriel. My first convo with him was how awesome his username was and how I wanted to take it, but he wasn't willing to change, so that's where my username Auraposle came from.
The second to last person is Aegis. I was viewing Erica's blog about Anime North and found him. It was about a few weeks after I started talking to Erica that I found them, I believe, because that's when she came back from Anime North. So I saw a picture of Camera Wars and saw that he was friends with her. I added him to MSN, and I think the first convo I had with him was how I was stalking him and I think he said that was pretty cool that he had a stalker. He's one of the people I talk to the most, after Morkula.
The -- real second to last person I wanted to talk to was Drummershuff. I really don't remember why I wanted to talk to him, but I did. I think it was because of his user title and the fact that he was friends with most of my friends. So, recently I added him to messenger, and he's... I think he's a pretty cool guy.
Finally, the person I want to become friends with now is Dawson. I've added him to messenger, and I see he's accepted it, but we've yet to speak to eachother.
These were the major people I've wanted to talk to and befriend. Through them, I've found other people who seemed cool and wanted to meet. So these are the main people, as I've stated.