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on bulbapedia it lists the catch rate and times to catch it as unknown. i'm on route 42 and i've been headbutting for a good 20 minutes. does anyone know if it's a day or morning only pokemon?
Ive encountered them at all times. It seems to be much rarer at night though, but like all pokemon that fall out of a tree at night after a headbutt, there's a good chance it'll be asleep.
Headbutt the trees in Azalea Town. That's where I got mine from.