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HP: Palpitoad, Stunfisk in Iccirus City (2 HP EVs each); Munna in Dreamyard (1 HP EV each)
Attack: Patrat and Lillipup in Route 1 (1 Attack EV each)
Defense: Roggenrola in Wellspring Cave; Sewaddle and Venipede in Pinwheel Forest (1 Defense EV each)
Special Attack: Litwick and Elgyem in Celestial Tower (1 Special Attack EV each)
Special Defense: Frillish (and Jellicent) by surfing in P2 Lab, Route 18 or Driftveil city (1 Special Defense EV for Frillish; 2 Special Defense EVs for Jellicent)
Speed: Woobat in Wellspring Cave (1 Speed EV each) or Basculin (surfing in lakes; 2 Speed EVs each)