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Bugsy, though I used to prefer Falkner. Tate and Liza are awesome, too, and I found myself really liking Burgh lately. None of the Kanto or Sinnoh leaders really stick out to me, unless maybe Sabrina and Volkner.
I hate to say this, but it's Whitney. I like how challenging she can be when fighting against her. After her, it's Erica, cuz she's cute and train Grass Type and finally in 3rd place, mah favorite is Cheren. I dunno, I just do. I like how he moves before you battle him.
For me it's Grimsley (mainly because he looks awesome in the Pokémon Adventures manga), Elesa, Skyla, N<3<3 (dunno if he counts LOL:pink_tongue:), and Iris (even though I didn't fight her, I just generally think she's cool!).
I would have to say Misty,Jasmin,Winona,Volkner,Skyla,Cheren and Brycen.
Skyla is by far my favorite out of all of those though. I like the other mainly because of the anime. I like Cheren just because and I like Brycen because he is an Ice Ninja and I love ninjas and ice types. I like Volkner because he is just awesome to me.
Since I love Ghost type Pokemon it is normal for me to gravitate to Ghost type gym leaders, so my two favorites will have to be Morty from Johto and Fantina from Sinnoh. Out of these two I would have to pick Fantina because she has purple hair like me.
Sabrina does it for me. The original Psychic-type Gym Leader? But of course. I'm also a fan of Whitney (though her Miltank always ticked me off in Pokemon Silver/Stadium 2), too.
Lt. Surge, Tate & Liza, and Winona are my favorites. Lt. Surge is just so patriotic, how can you not like him? And Tate & Liza are cool, finishing each other's sentences and what not. And Winona is my all-time favorite, because I like all of the Pokemon she uses.