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*points to Simple Questions where this has been answered before*
Islands 1-3 are accessible after beating Blaine, Bill offers you as trip to them.
Islands 4-7 are accessible after you get the National Dex (which you get by beating the Eleite Four and capturing 60 + Pokemon).
Islands 8-9 can only be gotten to via E-Cards.
Since this should be asked (and I am quite certain, has already been answered in) the stickied Simple Questions thread...