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I hope thats an azumarril. But anyway looking at your team you should do just fine as long as you keep chuckin those supereffective moves. However I dont think Simipour will be too much usefull. And you might have some trouble with the champion seing as your pokemon dont like like they can take to many hits, sans azumarill and eelektross
It depends on the moveset, you need an Ice-type move for the Champion, maybe on Simipour since
Azumarril is to slow and dosen't hit hard enough to deal with *spoiler* Dragon Dancing Haxorus.
I don't usually recommend two Pokemon of the same type.
Keep Simipour since its movepool is better than Azurill and unlike Huge Power Azumarill, Simipour can run mixed movesets (both physical and special) due to even Attack and Special Attack.
Unfezant isn't really that good of a Pokemon unless if you have the one with Super Luck, otherwise I'd recommend Braviary for a Flying-type (and you can catch one on Route 4 every Monday in White 2, in Black 2 a Mandibuzz is available there on Thursdays).