Talonflame's last 4 EVs should go into Defense, since putting them in HP makes its HP even, meaning it dies to 2 Stealth Rock switch-ins.
Sitrus Berry is preferred over Leftovers on Belly Drum Azumarill, so it can restore some HP upon using Belly Drum. 164 Speed EVs allow Azumarill to outspeed minimum Speed base 70s.
Gliscor should stick to defensive roles only. It's badly outclassed in offensive roles:
-Toxic
-Protect
-Earthquake
-Substitute/Knock Off
Nature: Impish
EVs: 252 HP/56 Def/200 Spe
Item: Toxic Orb
Ability: Poison Heal
or
-Earthquake
-Acrobatics
-Taunt/Toxic/Fling/Stealth Rock
-Roost
Nature: Impish
EVs: 252 HP/56 Def/200 Spe
Item: Toxic Orb
Ability: Poison Heal
or
-Earthquake/Knock Off
-Toxic/Knock Off/Stealth Rock
-Taunt/Stealth Rock
-Roost
Nature: Careful
EVs: 252 HP/184 SDef/72 Spe
Item: Toxic Orb
Ability: Poison Heal
Mega Alakazam can get away with a Modest nature because it still outspeeds +Speed base 130s with Modest:
-Psychic
-Shadow Ball
-Focus Blast
-Hidden Power (Fire/Ice)/Taunt/Substitute/Thunder Wave
Nature: Modest
EVs: 4 HP/252 SAtk/252 Spe
Item: Alakazite
Ability: Magic Guard (pre-Mega)
While it seems tempting to have Dragonite use Weakness Policy with Multiscale, it's not worth it in the end because since you lack Dragon Dance, it can get revenge killed if you can't Roost in time. Also, Dragonite's coverage moves are rather weak (Aerial Ace is a weak STAB and only Mega Aerodactyl gets away with it because of Tough Claws) and outside of Fairies, Iron Head is useless. Also, Dragonite can hit Fairies hard with Earthquake if needed and it loves the priority Extreme Speed provides:
-Outrage
-Extreme Speed
-Thunder Punch
-Superpower
Nature: Jolly
EVs: 252 Atk/4 Def/252 Spe
Item: Choice Band
Ability: Multiscale
or
-Dragon Dance
-Outrage
-Extreme Speed
-Earthquake/Fire Punch
Nature: Adamant
EVs: 252 Atk/4 Def/252 Spe
Item: Lum Berry
Ability: Multiscale
Brick Break is redundant with Earthquake on Excadrill, making the former useless. Drop it for Rock Slide, which is useful for nailing Mega Pinsir, Talonflame and Charizard (Y) on the switch. Assault Vest Excadrill uses an Adamant nature with a bulky spread of 120 HP/136 Atk/252 SDef.