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Playing Pokemon White I noticed that you can use theif on Game Freak Morimoto's elemental monkeys and steal their petaya berries, this can be done once a day.
What other trainers pokemon hold items that can be stolen?
When you battle Cheren in Victory Road each of his pokemon have an item
Gigalith - Leftovers
Unfeazant - Scope Lens
Haxorus - Dragon Gem
Liepard - Sitrus Berry
Simipour/Simisear/Simisage - Mystic Water/Charcoal/Miracle Seed
Samurott/Emboar/Serperior - Focus Sash
Thats all the trainers that I know of though. Alder, Bianca, N, Ghetsis and Cynthia all have no items