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I'd pick victreebel cos Its got a better move pool (aside from petal dance), it's attack is generally better though natures can change that, not to mention it looks much cooler :)
Victreebel is more of a physical attacker while Vileplume is built more to be a support pokemon. For in-game purposes, Victreebel will probably be more beneficial though. :P
I like Vileplume myself. I don't know why, but I've always liked it better than Victreebel. However, Vileplume is generally a support/annoyer Pokemon, while Victreebel is more about attacking. It really depends on what you're going for. If it doesn't matter, I'd go with what you think looks better :P.