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like a pokemon with high HP would benefit from holding a
Left Overs item.
some other good items are like
King's Rock
Scope Lens
Lax Incense
those are the 3 I generally use in the battle tower
the move type boosters aren't really all that useful.
i.e.
mystic water
hard stone
they're not so great, there's better items you can give a pokemon to hold
berries that cure status are decent hold items too
too bad there's no berry like "miracle berry" in ruby sapphire
or if there is I don't have it 'cuz I don't really use the berries too much
except when making pokeblocks to evolve my feebas.
It depends what type of Pokemon you have.
For example,when I bring an electric type
I give it MAGNET or if I have a water type i'll
give that Pokemon MYSTIC WATER