A random team for league

Level 100 is required for a good distribution of EVs ?

The levels of all your Pokemon are set back to 50 during online battle, so the distribution at level 50 is what you get. You wouldn't benefit from leveling all of your Pokemon up to 100.
 
They can, but only as long as you can afford to keep buying them. The easiest way to EV Train by and large will be Super Training. If you get ambitious, you can take on Horde Encounters with Power items.

This article might answer some additional questions that arise about Effort Values:

https://bulbapedia.bulbagarden.net/wiki/Effort_values#Generation_VI
 
Just question, how to know when an statistic is full in Ev ? (just one for 252 Evs)
It helps if you kinda keep track of it yourself, but the Super Training app will tell you that a Pokemon has maxed out the EVs in that stat if it's maxed out and you try to increase the EVs again.
 
My game card having retired of my 3ds alone in my pocket, and having not save, i must all restart of EV. Awesome !

Edit : 4/6 pokemon done !
 
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