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The only one I actually noticed recently was a female Snivy in White, I think the Pokemon quite suits that gender so was happy to have the rarer female varient for my playthrough!
My Chespin from my first playthrough of X and a Charmander from one of my LeafGreen playthoughs were female. The Shiny Squirtle I SR'd post-game in HGSS was female as well.
It's legit been at least a decade but I am pretty sure that my very first starter, my Pikachu in Yellow was female (via Stadium).
I also got a few females while soft resetting for a shiny Rowlet in Moon and presumably while soft resetting for a shiny Bulbasaur in Fire Red (the latter was a handful of years ago).
I remember quite well that my best friend had a female Typhlosion in Gold.
I actually have a huge track record with getting Female Starters.... about 4/6 of my starters since Gen 5 have been female and I haven't manipulated it in any way.
Someone transferred me a Charizard from Pokemon Blue to Pokemon Gold (via Time Capsule) and it turned out to be female. That's the closest I've been from having a female starter.